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Student Abstracts at SNL:

Exhaust Gas Recirculation Effects on Diesel Engine Soot Formation, Destruction, and Emissions. EDWIN HUESTIS (University of California, Davis, Davis, CA, 95616) MARK P. B. MUSCULUS (Sandia National Laboratory (California), Albuquerque, NM, 87185)

Diesel engine manufacturers desire insight into the internal processes that affect emissions in order to design new engines that meet upcoming US pollutant emissions regulations for particulate matter (soot) and nitrogen oxides (NOx). Exhaust gas recirculation (EGR) is one available tool to reduce pollutant emissions of NOx, and EGR has also been shown to reduce the formation of soot in fundamental combustion studies. In real engines, however, EGR can increase soot in the engine exhaust by affecting soot destruction processes after combustion. In this study, both exhaust-gas soot emissions and fundamental soot formation/destruction processes inside a diesel engine are measured to understand how these processes affect the ultimate soot emissions. The time-evolution of soot formation and destruction inside an optically accessible diesel engine is measured by analyzing the radiative emission spectrum of the combustion-heated soot. The soot radiative emission intensity is measured within two separate spectral bands, and along with high-speed luminosity movies, the soot temperature and concentration inside the engine are determined using the two-color soot thermometry technique. Gases are also sampled from the exhaust stream and drawn through a filter to collect the soot particles for exhaust-gas measurements. The measurements show that soot formation inside the engine decreased as EGR was added, but soot destruction processes decreased more rapidly, so that exhaust soot emissions increased as EGR was added. Only at very high EGR levels did the exhaust soot emissions decrease, as the soot formation processes became very slow. Finally, soot temperature measurements show that the reaction rates for soot formation and destruction depend on EGR, affecting the soot formation/destruction balance. By combining measurements inside the engine with exhaust-gas measurements, the effects of EGR on the soot formation/destruction balance were quantified in a single experimental facility. The data from this study shows that EGR decreases soot destruction processes more than soot formation processes, so that the balance is tipped toward higher exhaust soot. At very high EGR, however, soot formation processes are so slow that exhaust soot decreases, even with reduced rates of soot production. This study also identifies the tipping points where this balance shifts from increasing exhaust soot to decreasing exhaust soot.