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General Sciences Abstracts:

An Analysis of Chlorine Gas Release. KARA BROWN (University of California San Diego, La Jolla, CA, 92092) GEORGE FULTON (Lawrence Livermore National Laboratory, Livermore, CA, 94550)

Chlorine is an extremely reactive and harmful gas that can cause a myriad of health problems within seconds of exposure. This report is an analysis of current chlorine safety regulations in place at Lawrence Livermore National Laboratory for Building 153. It was found that the rapidity at which usable amounts of chlorine gas could be released into the main workspace of the building that the emergency response alarm for a leak needed to remain active. The calculations go through a series of different possibilities including the concentration of chlorine gas with multiple size cylinders, the difference that ventilation makes, and the amount of time it would take the ventilation to get the concentration of chlorine gas down to different airborne exposure standards such as the IDLH, STEL, 8-Hour TLV, or Mean Odor Threshold.

Arc Flash. YEVHEN RUTOVYTSKYY (Three Rivers Community College, Norwich, CT, 6360) SWAPNA MUKHERJI (Brookhaven National Laboratory, Upton, NY, 11973)

Analyzing BNL electrical distribution system. Determine the incident energy, boundary requirements, and the personal protective equipment necessary tin order to minimize the possibility of electric shock to personal. All the calculations are done by using PTW (Power Tools for Windows) software and based on measured data or information, obtained from the manufactures labels (such as: operating voltage, breaker size, size of the wire etc.) After completing this project we expect to come up with a universal label that will be posted on all electrical equipment that exists at BNL. New label will contain the name of the panel, warning statement "Arc Flash Hazard!!!" and category PPE (Personnel Protective Equipment)

Assessing the impact of aerosols on the radiation budget in the Sahel using the SHDOMPP Radiative Model. NIMISHA GHOSH ROY (University of Washington, Seattle, WA, 98006) TOM ACKERMAN (Pacific Northwest National Laboratory, Richland, WA, 99352)

To understand Earth’s dynamic climate system, scientists are developing global climate models. Currently there are various climate models that scientists are continuously trying to understand and refine. Current difficulties include the ability to correctly include the effect of aerosols and clouds in global climate models. The purpose of this project is to work on calculating the effect of aerosols (particles in the atmosphere) on the Earth’s radiation budget (the balance of incoming and outgoing solar radiation). This project focuses on the effects of aerosols in the Sahel (south of the Sahara Desert) with hopes of refining the way global climate models currently model the Sahel and similar regions. The instruments used are part of the Department of Energy’s Atmospheric Radiation Measurement Program’s mobile suite of instruments located in Niamey, Niger. The Sky Radiometer, Total Sky Imager and Micropulse Lidar were used to identify periods of clear skies on a time scale of fifteen minutes. Clear sky sets of data were critical because the presence of clouds in the data set would introduce too many variables. Various atmospheric properties were collected from a variety of instruments (also at Niamey, Niger) over the same periods of clear skies. Data used were from January 1 - 31st, 2006. The data was put into the SHDOMPP (Spherical Harmonics Discrete Ordinates Model, Plane-Parallel Version) Radiative Transfer Model. The model was run with two scenarios: 1) Clear Skies with Aerosols and 2) Clear Skies without Aerosols. Comparing the SHDOMPP model results with observed data from ground instruments provides a measure of the accuracy of the model. Initial results show a 1-5% agreement between modeled and observed calculations of total down welling shortwave flux. The two model runs (with and without aerosols) were compared to each other to understand the effect of the aerosols. Initial results show the presence of aerosol lowers the total down welling shortwave flux by 32 - 120 W/m2. Problems with the treatment of some input parameters have been identified. The next step in developing an understanding of the effect of aerosols will involve refining the assumptions and parameters input to the SHDOMPP model.

Development of Charged-Coupled Devices for Precision Cosmology and the Supernova Acceleration Probe Satellite. JESSICA WILLIAMSON (University of Alabama in Huntsville, Huntsville, AL, 35899) DR. NATALIE ROE (Lawrence Berkeley National Laboratory, Berkley, CA, 94720)

Dark energy, which is believed to be a cosmic energy density that is gravitationally repulsive and does not appear to cluster in galaxies, has been invoked to account for the recent measurement that the rate of the universe’s expansion is accelerating. To better understand these phenomena, scientists utilize type Ia supernovae as calibrated candles. Lawrence Berkeley National Laboratory (LBNL) is developing the Supernova Acceleration Probe (SNAP), a space-based telescope that will be used to identify and measure supernovae. The SNAP focal plane will consist of an innovative camera that integrates two cutting-edge imaging sensor systems, one of which is the LBNL high purity charged coupled device (CCD) for the visible light range. We report on the development of a novel technique for extending the spatial and photometric fidelity performance of the LBNL CCDs. Presented are our results obtained from measurements using a 10.5 µm pixel pitch, 1.4k×1.4k format, p channel CCD fabricated on high-resistivity silicon at LBNL. The fully depleted device is 300 µm thick and backside illuminated. Measurements of the device’s transverse diffusion of charge carriers, pixel to pixel uniformity and intrapixel uniformity will be reported. will be reported. Also presented are new, preliminary results from the first implementation of CCD Phase Dithering, a novel technique for achieving sub-pixel spatial resolution in undersampled, pixelated image data as will be obtained by the SNAP satellite.

Focal Mechanisms and Stress Axes of Microearthquakes in Southeastern Washington State. STEFANY SIT (Lawrence University, Appleton, WI, 54911) ALAN ROHAY (Pacific Northwest National Laboratory, Richland, WA, 99352)

The Hanford Seismic Network combined with the Eastern Washington Region Network covers eastern Washington State with forty-one seismograph stations. Routine analysis monitors and locates local seismic events dominated by shallow depth microearthquakes. However, regular study does not include investigations into the mechanisms of earthquakes. This report uses seismograms from 2000 to 2006 to develop constraints on fault and auxiliary planes of seismic activity occurring in southeastern Washington State. Through the proper identification of planes, the principal axes of stress can then be extrapolated. Using a SUN system and Focal2 software, focal mechanisms were developed according to the procedure provided by Oppenheimer (1996). A significant portion of the mechanisms showed a general maximum compression in the north-south direction with a low angle of plunge. The axis of minimum compression showed varying orientations with no conclusive pattern. These results are in agreement with previous studies done in the area and show no deviance from the historical pattern.

Inquiry-Based Learning at Its Best. SARAH BAUM (Lesley University, Cambridge, MA, 2138) MARY CONNOLLY (Lawrence Berkeley National Laboratory, Berkley, CA, 94720)

The Lawrence Hall of Science (LHS) is one of the leading forces in the inquiry-driven, direct experience approach to science and mathematics instruction for grades K-12. LHS has developed several inquiry-based curriculum projects that are used throughout the United States. This public science center also provides educational exhibits and classes, year-round outreach programs, as well as diverse summer camp programs for children of the region. The investigative approach stems from human beings’ natural curiosity to explore what is seen on a daily basis. This strategy when applied to a classroom helps students connect concrete ideas to their own experiences through open-ended investigations and discussions. My goal throughout the summer was to observe how instructors use guided inquiry techniques with a variety of age groups to delve into life, physical, and earth science. My research reflects an exploratory sample of age groups and content areas. Working alongside LHS instructors has allowed me to study inquiry-based education by observing, comparing, analyzing, and applying themes and elements central to the process.

Qualitative Testing of Social Network Analysis Biowarfare Taxonomy: An Analysis of LLNL Open Source Publications. LIRAN GOLDMAN (University of California, San Diego, La Jolla, CA, 92093) DEBORAH YARSIKE BALL AND DALE K. BREARCLIFFE (Lawrence Livermore National Laboratory, Livermore, CA, 94550)

The Dynamic Network Engineering Group takes a network-centric approach to discover and characterize organizational expertise and relationships of state and non-state actors intent on creating and using weapons of mass destruction (WMD). This approach utilizes a taxonomy that can identify and extract key actors from large, unstructured data sources. In this project, a taxonomy was developed and tested on a known entity: Lawrence Livermore National Laboratory (LLNL). The goal was to discover and qualitatively describe the results of a specific taxonomy when combined with the dynamic network analysis methods. The data used in this test analysis include a list of Livermore Laboratory employees who have a pager assigned to them, online versions of LLNL’s Science & Technology Review (S&TR), and a potential biowarfare taxonomy. After the S&TR issues were downloaded, the data were uploaded and processed in Automap, a program capable of extracting and analyzing computer based text by creating links among words then constructing a network. Next, the words of interest were extracted from the S&TR articles, and evaluated in Organization Risk Analyzer (ORA), a program capable of statistically analyzing dynamic networks. The analysis completed by ORA on this dataset revealed some key findings: the years 2003 and 2004 were prominent for biology related publications. Also, pathogens and anthrax were consistently the top areas explored. Follow-up analysis of these results indicates that this process is successful at singling out pertinent actors, but the results should be viewed with caution. A few drawbacks include Automap’s failure to extract variations of words the program is instructed to locate. Additionally, not all of the relationships established by Automap are valid due to its inability to distinguish between unrelated, yet adjacent articles. Furthermore, reporters who wrote the publications used in this test case became part of the data set. Also, the inclusion of projects and people is not a complete representation of ongoing research at LLNL. This latter issue is somewhat mitigated when examining external organizational expertise and relationships because the publications assessed are usually authored by the researchers themselves. These matters will be considered when applying this process to other datasets.

The effect of fire on soil carbon storage in a prairie ecosystem: applications to global climate change and ecosystem-climate feedbacks. RYAN SMITH (California State University Fresno, Fresno, CA, 93740) MARGARET TORN (Lawrence Berkeley National Laboratory, Berkley, CA, 94720)

The increasing concern around the topic of global warming is reason to assure climate change models be accurate. A potentially important omission from current models is CO2 feedbacks between climate and soils. Natural fire and managed fire both play an important role in maintaining the prairie ecosystem. If warming increases the frequency of fire it will be important to know the effect fire has on the storage of carbon in soil. The goal of this project was to investigate the effect of fire on soil carbon stocks in a prairie of the Southern Great Plains. Our null hypothesis was: no change in carbon content of grassland soil due to the fire treatment. The alternative hypothesis was that carbon content of the soil will decrease due to the treatment of fire. The USDA Grazing Research Laboratory in Oklahoma collaborated in this project and provided soil samples for analysis. Ten soil cores, 1 meter deep, were collected from two adjacent prairie fields in March 2005. Shortly after collection, the north field was treated with fire while the south field was left unburned to function as the experimental control. In August 2005, 10 more cores were collected from each of the two fields. Each core was divided into 10 cm depth increments from 0-50 and 25 cm increments below that, to look at the change in carbon content with depth. One half of the core was used to determine bulk density. The other half was used to test for carbonates and determine carbon content. No core tested positive for carbonates. For carbon analysis, the soil was homogenized and roots were removed. The carbon analysis showed that the content of carbon decreased with depth and that the greatest variability among cores was in the top 10 cm. Between March and August, the south field (unburned control) lost, 0.31 kg Carbon/m2 (p < 0.14 for the difference). In contrast, the north field showed an average total carbon stock loss of 1.1 kg Carbon/m2 after the treatment of fire. The loss of soil carbon in the burned field was highly significant (one-tailed p < 0.034) Assuming that the lost soil carbon was released to the atmosphere as CO2, these results suggest that there could be a strong positive feedback effect if warming increases fire frequency in prairie. Continued research on the rates of inputs and outputs of carbon into the soil-and the effect of fire on them-needs to be done to make whole conclusions.

The Laboratory Assessment Worksheet—A Risk Comparison of Biological and Chemical Hazards in the Laboratory. REBECCA WILLIAMSON (University of Virginia, Charlottesville, VA, 22556) GERALD SCHWEICKERT (Lawrence Livermore National Laboratory, Livermore, CA, 94550)

Today’s hazardous world demands safe work practices. An employee’s risk of injury and infection increases significantly when he handles sharps. To assess sharps use and compliance with correct safety controls and practices, the author generated a survey form. This form was based on current safety standards and used to conduct face-to-face interviews of Lawrence Livermore National Laboratory (LLNL) personnel who were using biological materials and sharps in research projects. At LLNL, current safety standards are summarized in what is known as the Environmental Safety and Health (ES&H) Manual. Close scrutinization of the ES&H manual confirmed consistency with the current sharps use standards. The Occupational Safety & Health Administration (OSHA) Bloodborne Pathogens Standard mandates that employers maintain a sharps injury log. The survey was designed to determine if any discrepancies between the number of sharps injuries sustained and those reported existed. However, the LLNL sharps injury log was not currently available but will be available in the future, and therefore such comparisons were not performed as part of this analysis. Twenty percent of the facilities using sharps at LLNL were evaluated. During the assessments, almost sixty percent of the labs had an observable sharps safety hazard. These safety breaches fell into one of the following three categories: improper recapping technique, presence of an exposed or improperly discarded sharp, or overfilled sharps container. Nearly twenty percent of the individuals interviewed either had injured himself with a sharp or knew of someone affiliated with his particular lab that had been injured. Seventy-five percent of the reported injuries occurred in a BSL-2 lab. Most researchers at LLNL use scalpels and needles. Half of the researchers reuse their sharps, a practice that should be avoided. The statistical results of the surveys alerted safety personnel to the need for sharps training and further evaluation of sharps use at LLNL.