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Faculty and Student Teams Program

questioning Project Descriptions

Pacific Northwest National Laboratory
Advanced Processing and Applications Group

Requesting applications from science or engineering faculty members at institutions serving students underrepresented in science, engineering, mathematics and technology.

Project Description

There are two projects on which the team(s) can work: 1) Phase Identification and Characterization in Chlorophosphate Waste Forms and 2) High-level Waste Glass Vitrification.

In the first of these projects, the team will use x-ray diffraction, differential thermal analysis, thermal gravimetric analysis, mass spectroscopy, and leach testing to identify and characterize materials that are candidates for special waste forms. The starting materials will be metal oxides/hydroxides that precipitate and become waste products from a process used to purify plutonium. In this study, no radioactive substances will be used; only inactive surrogates. These oxides/hydroxides contain substantial quantities of chloride salts. These mixtures are heated with a phosphate-containing materials to produce a ceramic material that serves as the waste form.

In the second project, two main topics will be studied: solid state reactions and property-composition relationships, both for multicomponent solid and molten mixtures, such as glass, glass-ceramics, and their batches. Thermoanalytical techniques will be used for solid-state reactions, those listed above plus others, such as differential scanning calorimetry, scanning electron microscopy, and evolved gas analysis with gas chromatograph and mass spectrometer. Based on the data, kinetic equations will be formulated for heterogeneous reactions and constitutive equations will be developed to characterize materials for mathematical models of processing technologies.

Applicants Responsibilities and Relationship to Project

Applicants will receive support under the Department of Energy Faculty Student Team Research Program (FaST) to work collaboratively with the project research team at the Pacific Northwest National Laboratory for up to 10 weeks during the year starting in June of 2006. Summer and academic year visits to Pacific Northwest will be scheduled by mutual agreement between the Advanced Processing and Applications Group and the successful applicant. Ideally faculty will work at Pacific Northwest on the project for 10 weeks during the summer in the first year. Faculty will be expected to identify students from their campus to participate in the Undergraduate Research Participation programs offered by the Department of Energy at Pacific Northwest National Laboratory. Ideally Faculty will provide mentorship and/or advising support to students during the summer research activities. It is expected that the Faculty member will become an integral part of the research team working on this project and will support the project through the academic year on her or his campus.

Qualifications of Ideal Candidate

Faculty: MS or PhD Degree in Chemistry, Materials Science. Currently teaching Chemistry or Materials Science
Student: Working towards a BS or BA in Chemistry or Materials Science. Works well in collaboration with faculty, other students, and researchers. Willing to work at PNNL for ten weeks in Summer 2006.

Support and Financial Commitments

See Financial Information.

For More Information contact:

Royace Aiken, Program Manager
Pacific Northwest National Laboratory
E-mail: royace.aikin@pnl.gov
(509) 375-6929
http://science-ed.pnl.gov/index.stm

Denis M. Strachan or Pavel Hrma
PO Box 999 (K6-24)
Pacific Northwest National Laboratory
Richland , WA
(509) 376-0677 or (509) 376-5092
denis.strachan@pnl.gov
pavel.hrma@pnl.gov