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Faculty and Student
Teams Program
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Project Descriptions
Pacific
Northwest National Laboratory
Applied Geology and Geochemistry Group
Requesting applications from science or engineering faculty members
at institutions serving students underrepresented in science, engineering,
mathematics and technology.
Project Description
The interactions of actinides with mineral surfaces will be studied.
Actual U contaminated soil samples will be examined to determine which
soil components are contaminated and to assess the chemical state of
U on/in these components. The binding strength of U at the surface will
be assessed. Vacuum based surface science techniques, such as Auger Electron
Spectroscopy (AES), X-ray Photoelectron Spectroscopy (XPS), Secondary
Ion Mass Spectrometry (SIMS) and Low Energy Electron Diffraction (LEED)
will be used. The interaction of uranium with the cleaved surface of
single crystal calcite will also be studied using the same techniques.
Calcite is a signficant Hanford soil component and is expected to interact
strongly with uranium. The cleaved surface of single crystal calcite
has been extensively studied. There have been some studies of the interaction
of U with this surface, but to date little progress has been made. The
U will be deposited from solution onto the surface. Use of this surface
will minimize the parameters that affect the U-surface interaction, such
as surface defects, crystal contaminants, etc. If time permits other
surfaces will be substituted for cleaved calcite. Other surfaces may
include stepped calcite surfaces or the surfaces of other relevant minerals
such as iron oxides/oxyhydroxides, aluminum oxides/oxyhydroxides, silicates,
aluminosilicates, etc.
Applicants Responsibilities and Relationship to Project
Applicants will receive support under the Department of Energy Faculty
Student Team Research Program (FaST) to work collaboratively with the
project research team at the Pacific Northwest National Laboratory for
up to 10 weeks during the year, starting in June 2006. Summer and academic
year visits to PNNL will be scheduled by mutual agreement between the
Radiochemical Science and Engineering Group and the successful applicant.
Ideally, faculty will work at PNNL on the project for 10 weeks during
the summer in the first year. Faculty will be expected to identify students
from their campus to participate in the Undergraduate Research Participation
programs offered by the Department of Energy at Pacific Northwest National
Laboratory. Faculty will provide mentorship and/or advising support to
students during the summer research activities. It is expected that the
faculty member will become an integral part of the research team working
on this project and will support the project through the academic year
on her or his campus.
Qualifications of Ideal Candidate
| Faculty: |
Professor must have an excellent understanding of Vacuum based
surface science techniques, such as Auger Electron Spectroscopy (AES),
X-ray Photoelectron Spectroscopy (XPS), Secondary Ion Mass Spectrometry
(SIMS) and Low Energy Electron Diffraction (LEED). |
| Student: |
Students with associated backgrounds in chemistry, soil science
and/or environmental science. |
Support and Financial Commitments
See Financial Information.
For More Information contact:
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